a) FIGURE 1 shows the mass spectrum of zirconium, Zr which has 40 protons.
i. Determine the relative atomic mass of zirconium.
[3 Marks]
ii. Write the isotopic notation when zirconium atom undergoes ionisation by losing four electrons.
[1 Mark]
b) An amount of 12.915 g of an organic compound containing carbon, hydrogen and oxygen was burned in excess oxygen. Analysis of the combustion revealed 18.942 g of carbon dioxide and 7.749 g of water were formed. Determine the empirical formula of the compound.
[5 Marks]
c) A reagent bottle contains a concentrated sulphuric acid solution with 98% by mass and a density of 1.83 gmL-1. Calculate the molarity of the acid
[4 Marks]
d) Potassium chlorate reacts with sulphur dioxide in an acidic medium according to the equation below. Balance the reaction equation by using ion-electron method
ClO3- + SO2 → SO42- + Cl-
[3 Marks]
e) Silicon nitride, Si3N4 is a very hard, high temperature resistant ceramic used as component of turbine blades in jet engines. It is produced according to the equation below:
3 Si (s) + 2 N2 (g) → Si3N4 (s)
i. Calculate the mass of Si3N4 produced when 20.00 g of Si and 15.00 g on N2 are reacted. .
[4 Marks]
ii. Determine the percentage yield if 24.75 g of Si3N4 is obtained in this reaction.
[2 Marks]